|
A practical demonstration of this is presented in the figure below. The resist chemistry illustrated there has the
unusual property that the acid catalyzed deprotection chemistry (a hydrolysis in this case) occurs in
minutes at room temperature, compared to a typical post-exposure bake requiring a temperature of 100
degrees C or more. Since, at room temperature, the rate of diffusion will be lowered, the
deprotection/diffusion rate ratio is this system is significantly increased compared to more conventional
systems. In practice, this resist chemistry has been experimentally measured1 to have a image blur only
one-third that of conventional CA resists. Images of this resist exposed using electron-beam
nanolithography2 are evidence that this resist chemistry is capable of resolving
features to at least the 30 nm dimensional scale.
References
- J.P. Cain, P.P. Naulleau,
E.M. Gullikson, C.J. Spanos, J. Vac. Sci. Techn. B, 24, 1234-1237, (2006)
- G. M. Wallraff, D. R. Medeiros, J. Bucchino, K. Petrillo, C. Rettner, Martha Sanchez,
W. Hinsberg, F. Houle, D. Goldfarb, Karen Temple, C. E. Larson, B. Davis, L. Sundberg, P. Brock,
J. A. Hoffnagle, S. Wind and Wu-Song Huang, J. Vac. Sci. Technol. B, 22, 3479-3484 (2004)
|